The solvolysis of a homopropargyl compound, 2,2-dimethyl-3-pentyn-1-yl tosylate
✍ Scribed by Joseph W. Wilson
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 137 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Recently we reprted about the first example of a 1.2-hydride shift durmg the generation of a vrnyl cation, a process well known for trlsubstituted car&mum ions 2) :Thls was obsermildurlng the solvolys~s of cls-and trans-3-cyclop~l-2-propen-2-yl-trifl~~~esulfo~~(tnflate)3! --The 1.2-hydride shLft was
Single-crystal X-ray study T = 294 K Mean (C-C) = 0.002 A Disorder in main residue R factor = 0.039 wR factor = 0.105 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
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