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Vinyl cations, 22 a 1,2-hydride shift in the solvolysis of 3-methyl-1-buten-2-yl triflate

✍ Scribed by Klaus-Peter Jäckel; Michael Hanack

Publisher: Elsevier Science
Year: 1975
Tongue: French
Weight: 137 KB
Volume: 16
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)91176-6

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✦ Synopsis

Recently we reprted about the first example of a 1.2-hydride shift durmg the generation of a vrnyl cation, a process well known for trlsubstituted car&mum ions 2) :Thls was obsermildurlng the solvolys~s of cls-and trans-3-cyclop~l-2-propen-2-yl-trifl~~~esulfo~~(tnflate)3! --The 1.2-hydride shLft was found to be a c r o s s the double bond.

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