✦ LIBER ✦
Organometallics in organic synthesis:tricarbonyl-(3-methoxycyclohexa-2,4-dien-1-yl)-iron(1+). A synthetic equivalent of the C-5 cation of cyclohexenone.
✍ Scribed by Lawrence F. Kelly; Peter Dahler; Acharan S. Narula; Arthur J. Birch
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 208 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Swrnnary: ~icarbonyZ-I3-methoxycyctohe~-2,4-dien-l-yl)-iro~l~l+~
PFcfl-) 2 reacts with a variety of nucleophiles to give 5-substi-&ted cyclohex-2-enones.
2 is sham to be a useful precursor for a convergent synthesis of 5-substituted cyclohcx-2-enones and to be synthetically equivalent to the 5-cyclohex-2-enone cation &.