On the melting point of 2,9-dimethyl-1,10-phenanthroline
β Scribed by Keihei Ueno; Mikihiko Saito; Hidekazu Iwano
- Book ID
- 118991265
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 105 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0039-9140
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
In the crystal structure of the title compound (BCP), C 26 H 20 N 2 , the phenyl rings are rotated out of the phenanthroline plane, with torsion angles of 119.66 ( 14) and 117.06 ( 14) . The asymmetric unit consists of one half BCP molecule, which is located on a crystallographic twofold rotation.
In the title compound, [Mn(C~7~H~5~O~3~)~2~(C~14~H~12~N~2~)]Β·C~14~H~12~N~2~Β·2H~2~O, the Mn^II^ ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two bidentate 3-hydroxybenzoate anions in a distorted octahedral environment. The structure is stabilized by OβH...O a