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(2,9-Dimethyl-1,10-phenanthroline)tetrahydroboratocopper(I)

✍ Scribed by Green, B. E. ;Kennard, C. H. L. ;Hawkins, C. J. ;Smith, G. ;James, B. D. ;White, A. H.

Book ID
114527219
Publisher
International Union of Crystallography
Year
1980
Weight
303 KB
Volume
36
Category
Article
ISSN
0567-7408

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📜 SIMILAR VOLUMES

2,9-Dimethyl-1,10-phenanthroline
2,9-Dimethyl-1,10-phenanthroline
✍ Smith, G. F.; McCurdy, W. H. 📂 Article 📅 1952 🏛 American Chemical Society 🌐 English ⚖ 375 KB
2,9-Dimethyl-4,7-diphenyl-1,10-phenanthr
2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline
✍ Wang, Jia ;Ye, Jun-Wei ;Wang, Yue 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 104 KB

In the crystal structure of the title compound (BCP), C 26 H 20 N 2 , the phenyl rings are rotated out of the phenanthroline plane, with torsion angles of 119.66 ( 14) and 117.06 ( 14) . The asymmetric unit consists of one half BCP molecule, which is located on a crystallographic twofold rotation.

Bis(2,9-dimethyl-1,10-phenanthroline)cop
Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) tetra­phenyl­borate dichloro­methane solvate
✍ Eckenhoff, William T. ;Pintauer, Tomislav 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 195 KB

In the title compound, [Cu(C~14~H~12~N~2~)~2~]C~24~H~20~B·CH~2~Cl~2~, Cu^I^ is chelated by two 2,9-dimethyl-1,10-phenanthroline (2,9-Me~2~phen) ligands, in a distorted tetrahedral coordination geometry. The average Cu—N bond length is 2.032 Å, and the interligand dihedral angle is 77.60 (6)°. The co