2,9-Dimethyl-1,10-phenanthroline
β Scribed by Smith, G. F.; McCurdy, W. H.
- Book ID
- 120282803
- Publisher
- American Chemical Society
- Year
- 1952
- Tongue
- English
- Weight
- 375 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0003-2700
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
In the crystal structure of the title compound (BCP), C 26 H 20 N 2 , the phenyl rings are rotated out of the phenanthroline plane, with torsion angles of 119.66 ( 14) and 117.06 ( 14) . The asymmetric unit consists of one half BCP molecule, which is located on a crystallographic twofold rotation.
In the title compound, [Mn(C~7~H~5~O~3~)~2~(C~14~H~12~N~2~)]Β·C~14~H~12~N~2~Β·2H~2~O, the Mn^II^ ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two bidentate 3-hydroxybenzoate anions in a distorted octahedral environment. The structure is stabilized by OβH...O a