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2,9-Dimethyl-1,10-phenanthroline

✍ Scribed by Smith, G. F.; McCurdy, W. H.


Book ID
120282803
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
375 KB
Volume
24
Category
Article
ISSN
0003-2700

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2,9-Dimethyl-4,7-diphenyl-1,10-phenanthr
✍ Wang, Jia ;Ye, Jun-Wei ;Wang, Yue πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 104 KB

In the crystal structure of the title compound (BCP), C 26 H 20 N 2 , the phenyl rings are rotated out of the phenanthroline plane, with torsion angles of 119.66 ( 14) and 117.06 ( 14) . The asymmetric unit consists of one half BCP molecule, which is located on a crystallographic twofold rotation.

(2,9-Dimethyl-1,10-phenanthroline-ΞΊ2N,Nβ€²
✍ Xuan, Xiao-peng ;Zhao, Pei-zheng ;Zhang, Shu-xia πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 590 KB

In the title compound, [Mn(C~7~H~5~O~3~)~2~(C~14~H~12~N~2~)]Β·C~14~H~12~N~2~Β·2H~2~O, the Mn^II^ ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two bidentate 3-hydroxybenzoate anions in a distorted octahedral environment. The structure is stabilized by Oβ€”H...O a