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On the impedance of galvanic cells: XI. The impedance of the Hg/Hg2++ electrode in 1 M and 0.1 M HClO4

โœ Scribed by M. Sluyters-Rehbach; J. H. Sluyters

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
273 KB
Volume
83
Category
Article
ISSN
0165-0513

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๐Ÿ“œ SIMILAR VOLUMES

On the impedance of galvanic cellsโ€”XVII.
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A theory is presented of the complex behaviour of the streaming zinc amalgam electrode in a Zns+ solution. It is assumed that the Znp+/Zn+ and the Zn+/Zn(Hg) electrode reactions occur at potentials where at the dropping amalgam electrode the Zna+-resp. Zn-concentration at the electrode surface is vi

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The discharge of K+ ions at the dropping mercury electrode (dme) in 1 M KC1 solution at 25ยฐC has been studied by means of analysis of the electrode impedance at different frequencies, using the complex plane method. It is shown that the electrode reaction is almost entirely diffusioncontrolled, but

On the impedance of galvanic cells: VIII
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โœ M. Sluyters-Rehbach; B. Timmer; J. H. Sluyters ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 409 KB

## Abstract The anomalous behaviour of the Tl^+^/Tl(Hg) electrode in 1 KNO~3~ + 0.1 __M__ KCl solution has been studied experimentally applying the theory described in parts IV and VI of this series. It is shown that this anomaly can be explained assuming that the double layer capacity increases on