๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

On the impedance of galvanic cells: VIII. The abnormal behaviour of the Tl+/Tl(Hg) electrode

โœ Scribed by M. Sluyters-Rehbach; B. Timmer; J. H. Sluyters

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
409 KB
Volume
82
Category
Article
ISSN
0165-0513

No coin nor oath required. For personal study only.

โœฆ Synopsis

Abstract

The anomalous behaviour of the Tl^+^/Tl(Hg) electrode in 1 KNO~3~ + 0.1 M KCl solution has been studied experimentally applying the theory described in parts IV and VI of this series. It is shown that this anomaly can be explained assuming that the double layer capacity increases on adding thallous ions. The increase ฮ” C appears to be proportional to the TI^+^ concentration. The phase angle ฮฆ of the faradaic impedance is equal to ฯ€/4.

๐Ÿ“œ SIMILAR VOLUMES

On the impedance of galvanic cellsโ€”XVII.
On the impedance of galvanic cellsโ€”XVII. The mechanism of the Zn2+/Zn(Hg) electrode reaction
โœ M. Sluyters-Rehbach; A.B. Ijzermans; B. Timmer; J.B. Griffioen; J.H. Sluyters ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 838 KB

A theory is presented of the complex behaviour of the streaming zinc amalgam electrode in a Zns+ solution. It is assumed that the Znp+/Zn+ and the Zn+/Zn(Hg) electrode reactions occur at potentials where at the dropping amalgam electrode the Zna+-resp. Zn-concentration at the electrode surface is vi

On the impedance of galvanic cells: V. T
On the impedance of galvanic cells: V. The impedance of a galvanic cell with two plane parallel electrodes at short distance
โœ J. H. Sluyters ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 276 KB

## Abstract It is shown both by calculation and experimentally that in a galvanic cell with two plane electrodes, through which an alternating current flows, the concentration waves interfere if the distance of the electrodes is of the order of a wave length.