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On the impedance of galvanic cells: X. The impedance of the H⊕/H2(Hg) electrode in 1 M perchloric acid

✍ Scribed by M. Sluyters-Rehbach; J. H. Sluyters

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
168 KB
Volume
83
Category
Article
ISSN
0165-0513

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A theory is presented of the complex behaviour of the streaming zinc amalgam electrode in a Zns+ solution. It is assumed that the Znp+/Zn+ and the Zn+/Zn(Hg) electrode reactions occur at potentials where at the dropping amalgam electrode the Zna+-resp. Zn-concentration at the electrode surface is vi

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## Abstract If, at one particular frequency, the electrode impedance is plotted in the complex impedance plane at varying bulk concentrations C\*ox and C\*RED, keeping C\*ox = C\*RED, a circle is obtained. Moreover, through one of the points measured a semicircle can be drawn with its centre on the