The title compound, C 11 H 15 NOS, was prepared by the reaction of phenyl isothiocyanate with isobutyl alcohol at room temperature. The central CNC( S)O group is essentially planar. In the crystal structure, the molecules are connected via N-HÁ Á ÁS interactions.
O-Methyl N-phenylthiocarbamate
✍ Scribed by Ho, Soo Yei ;Lai, Chian Sing ;Tiekink, Edward R. T.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 153 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The central CNC( S)O entity in MeOC( S)N(H)Ph, C 8 H 9 NOS, is effectively planar and shows that the molecule exists as a thione. In the crystal structure, molecules related by a centre of symmetry are associated via NÐHÁ Á ÁS interactions, forming thioamide dimers.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.034 wR factor = 0.097 Data-to-parameter ratio = 12.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C~13~H~12~N~2~OS, was prepared by the reaction of (4-pyridyl)methanol with phenyl isothiocyanate and NaOH in a 1,4-dioxane solution. The asymmetric unit contains two independent molecules. The molecular structure and packing are stabilized by N—H...N intermolecular hydrogen-bond
The title compound, C 10 H 13 NOS, displays an E conformation about the central C-N bond and exists in the thione form. N-HÁ Á ÁS hydrogen-bonding interactions link centrosymmetrically related molecules into dimers. organic papers o1886 Tadbuppa and Tiekink C 10 H 13 NOS
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.047 wR factor = 0.114 Data-to-parameter ratio = 21.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.