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O-Isobutyl N-phenyl­thio­carbamate

✍ Scribed by Jian, Fang-Fang ;Yu, Huan-Qing ;Qiao, Yuan-Biao ;Liang, Tong-Ling

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
133 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 11 H 15 NOS, was prepared by the reaction of phenyl isothiocyanate with isobutyl alcohol at room temperature. The central CNC( S)O group is essentially planar. In the crystal structure, the molecules are connected via N-HÁ Á ÁS interactions.

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O-Methyl N-phenyl­thio­carbamate
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.034 wR factor = 0.097 Data-to-parameter ratio = 12.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The title compound, C~13~H~12~N~2~OS, was prepared by the reaction of (4-pyridyl)methanol with phenyl isothiocyanate and NaOH in a 1,4-dioxane solution. The asymmetric unit contains two independent molecules. The molecular structure and packing are stabilized by N—H...N intermolecular hydrogen-bond

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The title compound, C 10 H 13 NOS, displays an E conformation about the central C-N bond and exists in the thione form. N-HÁ Á ÁS hydrogen-bonding interactions link centrosymmetrically related molecules into dimers. organic papers o1886 Tadbuppa and Tiekink C 10 H 13 NOS