The central CNC( S)O entity in MeOC( S)N(H)Ph, C 8 H 9 NOS, is effectively planar and shows that the molecule exists as a thione. In the crystal structure, molecules related by a centre of symmetry are associated via NÐHÁ Á ÁS interactions, forming thioamide dimers.
(4-Pyridyl)methyl N-phenylthiocarbamate
✍ Scribed by Xiao, Hai-Lian ;Wang, Ke-Fei ;Jian, Fang-Fang
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 69 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C~13~H~12~N~2~OS, was prepared by the reaction of (4-pyridyl)methanol with phenyl isothiocyanate and NaOH in a 1,4-dioxane solution. The asymmetric unit contains two independent molecules. The molecular structure and packing are stabilized by N—H...N intermolecular hydrogen-bond interactions and C—H...π interactions.
📜 SIMILAR VOLUMES
The title compound, C 10 H 13 NOS, displays an E conformation about the central C-N bond and exists in the thione form. N-HÁ Á ÁS hydrogen-bonding interactions link centrosymmetrically related molecules into dimers. organic papers o1886 Tadbuppa and Tiekink C 10 H 13 NOS
The title compound, C 8 H 10 N 2 O 2 , is nearly planar. The crystal packing is stabilized by N-HÁ Á ÁN hydrogen bonds.