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(4-Pyrid­yl)methyl N-phenyl­thio­carbamate

✍ Scribed by Xiao, Hai-Lian ;Wang, Ke-Fei ;Jian, Fang-Fang


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
69 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, C~13~H~12~N~2~OS, was prepared by the reaction of (4-pyridyl)methanol with phenyl isothiocyanate and NaOH in a 1,4-dioxane solution. The asymmetric unit contains two independent molecules. The molecular structure and packing are stabilized by N—H...N intermolecular hydrogen-bond interactions and C—H...π interactions.


📜 SIMILAR VOLUMES


O-Methyl N-phenyl­thio­carbamate
✍ Ho, Soo Yei ;Lai, Chian Sing ;Tiekink, Edward R. T. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 153 KB

The central CNC( S)O entity in MeOC( S)N(H)Ph, C 8 H 9 NOS, is effectively planar and shows that the molecule exists as a thione. In the crystal structure, molecules related by a centre of symmetry are associated via NÐHÁ Á ÁS interactions, forming thioamide dimers.

(E)-O-Ethyl N-(4-methyl­phen­yl)thio­car
✍ Tadbuppa, Primjira P. ;Tiekink, Edward R. T. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 138 KB

The title compound, C 10 H 13 NOS, displays an E conformation about the central C-N bond and exists in the thione form. N-HÁ Á ÁS hydrogen-bonding interactions link centrosymmetrically related molecules into dimers. organic papers o1886 Tadbuppa and Tiekink C 10 H 13 NOS

Ethyl N-(2-pyrid­yl)carbamate
✍ Zheng, Peng-Wu ;Wang, Wei ;Duan, Xue-Min 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 124 KB

The title compound, C 8 H 10 N 2 O 2 , is nearly planar. The crystal packing is stabilized by N-HÁ Á ÁN hydrogen bonds.

N-Hexanoyl-N′-(6-methyl-2-pyrid­yl)thio­
✍ Yusof, M. Sukeri M. ;Yaakob, Wan Nur Aishah ;Kadir, Maisara A. ;Yamin, Bohari M. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 296 KB