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(E)-O-Ethyl N-(4-methyl­phen­yl)thio­carbamate

✍ Scribed by Tadbuppa, Primjira P. ;Tiekink, Edward R. T.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
138 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, C 10 H 13 NOS, displays an E conformation about the central C-N bond and exists in the thione form. N-HÁ Á ÁS hydrogen-bonding interactions link centrosymmetrically related molecules into dimers. organic papers o1886 Tadbuppa and Tiekink C 10 H 13 NOS


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(E)-O-Ethyl N-(4-nitro­phen­yl)thio­carb
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Single-crystal X-ray study T = 150 K Mean (C-C) = 0.003 A R factor = 0.052 wR factor = 0.162 Data-to-parameter ratio = 25.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

(4-Pyrid­yl)methyl N-phenyl­thio­carbama
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The title compound, C~13~H~12~N~2~OS, was prepared by the reaction of (4-pyridyl)methanol with phenyl isothiocyanate and NaOH in a 1,4-dioxane solution. The asymmetric unit contains two independent molecules. The molecular structure and packing are stabilized by N—H...N intermolecular hydrogen-bond