(E)-O-Ethyl N-(4-methylphenyl)thiocarbamate
✍ Scribed by Tadbuppa, Primjira P. ;Tiekink, Edward R. T.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 138 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The title compound, C 10 H 13 NOS, displays an E conformation about the central C-N bond and exists in the thione form. N-HÁ Á ÁS hydrogen-bonding interactions link centrosymmetrically related molecules into dimers. organic papers o1886 Tadbuppa and Tiekink C 10 H 13 NOS
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 150 K Mean (C-C) = 0.003 A R factor = 0.052 wR factor = 0.162 Data-to-parameter ratio = 25.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C~13~H~12~N~2~OS, was prepared by the reaction of (4-pyridyl)methanol with phenyl isothiocyanate and NaOH in a 1,4-dioxane solution. The asymmetric unit contains two independent molecules. The molecular structure and packing are stabilized by N—H...N intermolecular hydrogen-bond