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Novel skeletal rearrangement in addition reaction to tricyclo[4,2,2,02,5]deca-3,7-diene system

✍ Scribed by Nicolai S. Zefirov; V.N. Kirin; A.S. Kozmin; I.V. Bodrikov; K.A. Potekhin; E.N. Kurkutova

Publisher: Elsevier Science
Year: 1979
Tongue: French
Weight: 206 KB
Volume: 20
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)86203-1

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✦ Synopsis

The "doping-a,-Jdition" of RSCl to the tricyclo[4,2,2,0 2,51 ~deca-3,7-diene derivatives which are incapable of lactone ring closure proceeds to give the 'love1 type of rec3rranged product, x, due to the two subsequent 1,2-shifts.

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