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Novel stereospecific syn addition of iodine azide to a strained cyclobutene (tricyclo[4.2.2.02,5]deca-3,7-diene derivative)

โœ Scribed by Goverdhan Mehta; Prabir K. Dutta; Paras N. Pandey

Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
103 KB
Volume
16
Category
Article
ISSN
0040-4039

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Novel skeletal rearrangement in addition
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โœ Nicolai S. Zefirov; V.N. Kirin; A.S. Kozmin; I.V. Bodrikov; K.A. Potekhin; E.N. ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 206 KB

The "doping-a,-Jdition" of RSCl to the tricyclo[4,2,2,0 2,51 ~deca-3,7-diene derivatives which are incapable of lactone ring closure proceeds to give the 'love1 type of rec3rranged product, x, due to the two subsequent 1,2-shifts.