A revised mechanism for thermal rearrangement of some tricyclo[4.2.2.02,5]deca-3,7,9-trienes
โ Scribed by Edwin Vedejs
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 202 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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doping-addition" of 2-N02C6H4SG1 to the tricyclo[4,2,2,0295]deca-3,7,+trj\_ene system ~\_occurs to give unusual products: (i) rearanged caged cyclopropane Aand (ii) the stable cross-PerChlOrate &
It was recently reported that the acetone-sensitized photoisomerisation of anti-7,8-beneotricyclo[4.2.2.0295 ]deca-3,7,9-triene (1) yields beneobasketene (2) and tetracyclic isomer (3).1 We now wish to describe our related studies on the photosensitiaed isomerization of (1) and some related compoun
## 500001 (India) New syntheses of tricycle [4.2.2.0285] deca-3,7-dien-g-one are described. Direct and sensftised photolysis of this ring system provides facile entry to several novel polycyclic~.