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Doping-addition of arylsulfenyl chlorides to the tricyclo[4,2,2,02,5]deca-3,7,9-triene system: skeletal rearrangements and serendipitious products

✍ Scribed by Nikolai S. Zefirov; A.S. Koz'min; V.V. Zhdankin; V.N. Kirin; I.V. Bodrikov; B.B. Sedov; V.G. Rau

Publisher: Elsevier Science
Year: 1979
Tongue: French
Weight: 245 KB
Volume: 20
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)95454-1

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✦ Synopsis

doping-addition" of 2-N02C6H4SG1 to the tricyclo[4,2,2,0295]deca-3,7,+trj_ene system ~_occurs to give unusual products: (i) rearanged caged cyclopropane Aand (ii) the stable cross-PerChlOrate &

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Novel skeletal rearrangement in addition

Novel skeletal rearrangement in addition reaction to tricyclo[4,2,2,02,5]deca-3,7-diene system

✍ Nicolai S. Zefirov; V.N. Kirin; A.S. Kozmin; I.V. Bodrikov; K.A. Potekhin; E.N. 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 206 KB

The "doping-a,-Jdition" of RSCl to the tricyclo[4,2,2,0 2,51 ~deca-3,7-diene derivatives which are incapable of lactone ring closure proceeds to give the 'love1 type of rec3rranged product, x, due to the two subsequent 1,2-shifts.