Photochemistry of tricyclo [4.2.2.02,5] deca-3,7-dien-9-one: a source of many interesting polycycles
β Scribed by Goverdhan Mehta; A. Srikrishna
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 262 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
500001 (India)
New syntheses of tricycle [4.2.2.0285] deca-3,7-dien-g-one are described.
Direct and sensftised photolysis of this ring system provides facile entry to several novel polycyclic~.
π SIMILAR VOLUMES
Recently, Cargill and coworkers1 have reported that irradiation of antitricyclo[5.2.0.0 285]nona-3,8-dien-9-one(I)l'2 in methylenechloride with "black-CI, lights" gives homocubane as a major product. However, it may be expected that
It was recently reported that the acetone-sensitized photoisomerisation of anti-7,8-beneotricyclo[4.2.2.0295 ]deca-3,7,9-triene (1) yields beneobasketene (2) and tetracyclic isomer (3).1 We now wish to describe our related studies on the photosensitiaed isomerization of (1) and some related compoun