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Asymmetric desymmetrization of a Pseudo-mesoendo-tricyclo[5.2.1.02,6]deca-4,8-dien-3-one by chiral amines

✍ Scribed by Frank J.A.D. Bakkeren; Namakkal G. Remesh; Debby de Groot; Antonius J.H. Klunder; Binne Zwanenburg

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
309 KB
Volume
37
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Asymmetric Desymmet
ChemInform Abstract: Asymmetric Desymmetrization of a Pseudo-meso endo-Tricyclo(5.2.1.02,6) deca-4,8-dien-3-one by Chiral Amines.
✍ F. J. A. D. BAKKEREN; N. G. RAMESH; D. DE GROOT; A. J. H. KLUNDER; B. ZWANENBURG πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 1 views

## Asymmetric Desymmetrization of a Pseudo-meso endo-Tricyclo(5.2.1.02,6) deca-4,8-dien-3-one by Chiral Amines. -The title compound (I) undergoes a dynamic kinetic resolution to enaminones (III) applying prolinol or its methyl ether as chiral mediators. Reductive elimination of the chiral auxilia

ChemInform Abstract: Synthesis and Struc
ChemInform Abstract: Synthesis and Structure Elucidation of 8-Methyl- and 9-Methyl-exo-2- carbomethoxy-endo-tricyclo(5.2.1.02,6)deca-3,8-dien-5-ones.
✍ S. C. SURI; A. C. CABRERA; E. J. WUCHERER; S. L. RODGERS πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 1 views

Synthesis and Structure Elucidation of 8-Methyl-and 9-Methylexo-2-carbomethoxy-endo-tricyclo(5.2.1.02,6)deca-3,8-dien-5-ones. -The unseparable mixture of 1-and 2-methyl-tetrahydro-1,4-methanonaphthalenediones (I) and (II), resp., obtained by thermal cracking of methylcyclopentadiene dimer and trappi

Reactions of 1,3,5-Tri-tert-butylcyclope
Reactions of 1,3,5-Tri-tert-butylcyclopentadiene formation of a tetracyclo[5.2.1.02,6.03,10]deca-4,8-diene
✍ Dehmlow, Eckehard V. ;Bollmann, Christof πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 332 KB

Title compound 1 is sterically shielded to such an extent that many "normal" reactions cannot occur. It is possible, however, to prepare the carboxylic acid 2, its acyl chloride 3 and the oxidation product 4. Furthermore, halogen substitutions to yield 5 and 6 and trialkylstannations to give 8a, b c

The photochemistry of anti-tricyclo[5.2.
The photochemistry of anti-tricyclo[5.2.0.02,5]nona-3,8-dien-9-one. Formation of tetracylo[6.1.0.2,9.0 4,7]-5-en-3-one.
✍ Kazuyuki Yano πŸ“‚ Article πŸ“… 1974 πŸ› Elsevier Science 🌐 French βš– 101 KB

Recently, Cargill and coworkers1 have reported that irradiation of antitricyclo[5.2.0.0 285]nona-3,8-dien-9-one(I)l'2 in methylenechloride with "black-CI, lights" gives homocubane as a major product. However, it may be expected that

ChemInform Abstract: Synthesis of 1-Subs
ChemInform Abstract: Synthesis of 1-Substituted 2-Azaspiro[4.5]deca-6,9-diene-8-ones and 2-Azaspiro[4.5]deca-1,6,9-triene-8-ones by a Three-Component Condensation of 1,2,3-, 1,2,4- or 1,3,5-Trimethoxybenzene with Isobutyric Aldehyde and Nitriles.
✍ Vladimir A. Glushkov; Olga G. Stryapunina; Alexey A. Gorbunov; Olga A. Maiorova; πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 61 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v