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The photochemistry of anti-tricyclo[5.2.0.02,5]nona-3,8-dien-9-one. Formation of tetracylo[6.1.0.2,9.0 4,7]-5-en-3-one.

✍ Scribed by Kazuyuki Yano

Publisher: Elsevier Science
Year: 1974
Tongue: French
Weight: 101 KB
Volume: 15
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)93154-5

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✦ Synopsis

Recently, Cargill and coworkers1 have reported that irradiation of antitricyclo[5.2.0.0 285]nona-3,8-dien-9-one(I)l'2 in methylenechloride with "black-CI, lights" gives homocubane as a major product.

However, it may be expected that

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