In the title compound, C~10~H~8~BrN~3~, the dihedral angle between the pyridine ring planes is 6.10 (15)°. In the crystal structure, the molecules are linked by N—H...N hydrogen bonds, leading to chains.
N,N-Diethyl-5-nitropyridin-2-amine
✍ Scribed by Yufit, Dmitry S. ;Turner, Michael J. ;Howard, Judith A. K.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 362 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C~9~H~13~N~3~O~2~, the asymmetric unit contains two almost identical but crystallographically independent molecules. The molecules are linked together by pairs of weak C—H...O interactions into zigzag chains, which, in turn, form corrugated layers perpendicular to the a axis.
📜 SIMILAR VOLUMES
A new bis(pyridyl) compound, C 18 H 14 N 4 , was prepared by the reaction of phthalaldehyde and 2-aminopyridine in toluene. In the crystal structure,stacking interactions exist between two adjacent molecules. ## Related literature Two corresponding complexes with 5-methyl-4,5-dihydroisoxazol-3-yl
Two compounds were obtained via the addition of Nmethylhydroxylamine to 1-phenyl-2-nitropropene. The structure of the major product, the title compound, (I), C 17 H 17 N 3 O 6 , is reported here. Both asymmetric C atoms (C1 and C2) have the same chirality, either R,R or S,S.
The molecule of the title compound, a Schiff base, C 9 H 7 ClN 2 S 2 , is roughly planar, with the two rings twisted by only 8.8 . Molecules are interconnected by weak C-HÁ Á ÁS interactions leading to the formation of chains parallel to the c axis. Weak slippedstacking between the thiophene rings m