✦ LIBER ✦

N-[(5-Chlorothiophen-2-yl)methylene]-5-methylthiazol-2-amine

✍ Scribed by Zhang, Chun-Niu ;Zheng, Yun-Fa

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 365 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807030255

No coin nor oath required. For personal study only.

✦ Synopsis

The molecule of the title compound, a Schiff base, C 9 H 7 ClN 2 S 2 , is roughly planar, with the two rings twisted by only 8.8 . Molecules are interconnected by weak C-HÁ Á ÁS interactions leading to the formation of chains parallel to the c axis. Weak slippedstacking between the thiophene rings may help in further stabilizing the packing (centroid-tocentroid distance = 3.947 A ˚, interplanar distance = 3.651 A ånd offset angle = 22.3 ).

📜 SIMILAR VOLUMES

(E)-N-[(5-Bromothiophen-2-yl)methylene]-

(E)-N-[(5-Bromothiophen-2-yl)methylene]-5-methylthiazol-2-amine

✍ Gu, Yong-Bing ;Zhang, Chun-Niu ;Yang, Ming-Hua 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 519 KB

5-[(5-Methylthiazol-2-yl)diazenyl]pyr

5-[(5-Methylthiazol-2-yl)diazenyl]pyrimidine-2,4,6(1H,3H,5H)-trione

✍ Hökelek, Tuncer ;Seferoğlu, Zeynel ;Şahin, Ertan ;Ertan, Nermin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 154 KB

In the molecular structure of the title compound, C~8~H~7~N~5~O~3~S, the thiazole ring is oriented with respect to the barbituric acid ring at a dihedral angle of 5.14 (9)°. In the crystal structure, intermolecular N—H...N and N—H...O hydrogen bonds link the molecules, forming a layer parallel to th

2,2-Dimethyl-5-[(4-methylthiazol-2-yla

2,2-Dimethyl-5-[(4-methylthiazol-2-ylamino)methylene]-1,3-dioxane-4,6-dione

✍ da Silva, Luiz Everson ;Joussef, Antonio Carlos ;Andrighetti-Fröhner, Carla Regi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 240 KB

N,N-Diethyl-5-nitropyridin-2-amine

✍ Yufit, Dmitry S. ;Turner, Michael J. ;Howard, Judith A. K. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 362 KB

In the title compound, C~9~H~13~N~3~O~2~, the asymmetric unit contains two almost identical but crystallographically independent molecules. The molecules are linked together by pairs of weak C—H...O interactions into zigzag chains, which, in turn, form corrugated layers perpendicular to the __a__ ax

2′-[(5-Chloro-1H-indol-3-yl)methylene]-

2′-[(5-Chloro-1H-indol-3-yl)methylene]-2-(1H-indol-3-yl)acetohydrazide

✍ Ali, Hapipah M. ;Nazzatush Shimar, Jamaludin ;Wan Jefrey, Basirun ;Ng, Seik Weng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 201 KB

N-(2,5-Dichlorophenyl)-N′-[(E)-3-thien

N-(2,5-Dichlorophenyl)-N′-[(E)-3-thienylmethylene]hydrazine

✍ Sonar, Vijayakumar N. ;Parkin, Sean ;Crooks, Peter A. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 158 KB

The title compound, C 11 H 8 Cl 2 N 2 S, was prepared from the condensation reaction of thiophene-3-carbaldehyde with 2,5dichlorophenylhydrazine. The azomethine C N bond has E geometry. No thienyl ring flip was observed.