Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.003 A Ê R factor = 0.039 wR factor = 0.088 Data-to-parameter ratio = 12.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
N,N-(2-benzothiazole)(2-pyridylmethyl)amine
✍ Scribed by Chen, Zhen-Feng ;Tang, Yun-Zhi ;Shi, Shao-Ming ;Wang, Xian-Wen ;Liang, Hong ;Yu, Kai-Bei
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 202 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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In the title complex, [CoCl~2~(C~7~H~6~N~2~S~4~)], 2,2′-(methylenedithio)bi-1,3-thiazole acts as a bidentate ligand and chelates one Co^II^ ion through the two N atoms to give an eight-membered symmetric unit. The Co^II^ ion is located on a twofold axis and displays a slightly distorted tetrahedral
Single-crystal X-ray study T = 113 K Mean '(C±C) = 0.005 A Ê R factor = 0.056 wR factor = 0.163 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.035 wR factor = 0.076 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title vanadium complex, [VClO(C 16 H 22 N 4 )]ClO 4 , of the tetradentate ligand N,N H -dimethyl-N,N H -bis(2-pyridylmethyl)ethane-1,2-diamine was obtained from air oxidation of a mixture of the ligand and VCl 3 in wet methanol.