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Dichloro[2,2′-(methylenedithio)bi-1,3-thiazole-κ2N,N′]cobalt(II)

✍ Scribed by Zhao, Wen-Tao ;Liu, Hui-Min ;Zhang, Wen-Qin

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 248 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536806022562

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✦ Synopsis

In the title complex, [CoCl~2~(C~7~H~6~N~2~S~4~)], 2,2′-(methylenedithio)bi-1,3-thiazole acts as a bidentate ligand and chelates one Co^II^ ion through the two N atoms to give an eight-membered symmetric unit. The Co^II^ ion is located on a twofold axis and displays a slightly distorted tetrahedral coordination environment, where the two Cl^−^ anions occupy the remaining coordination sites. The N—Co—N and Cl—Co—Cl planes are nearly perpendicular, with a dihedral angle of 88.0 (3)°.

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✦ Synopsis

Dichloro[2,2′-(methylenedithio)bi-1,3-thiazole-κ2N,N′]cobalt(II)