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N-Heterocyclic Carbene–Palladium Complexes as Efficient Catalysts for the Oxidative Carbonylation of Amines to Ureas

✍ Scribed by Shuzhan Zheng; Xingao Peng; Jianming Liu; Wei Sun; Chungu Xia


Publisher
John Wiley and Sons
Year
2007
Tongue
German
Weight
69 KB
Volume
90
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

A highly efficient oxidative carbonylation reaction of amines to ureas was developed making use of carbene–palladium complexes in the absence of any promoter. Both aliphatic amines and aromatic amines were transformed in good to excellent yields to the expected ureas.


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