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(NHC)CuI (NHC: N-Heterocyclic Carbene) Complexes as Efficient Catalysts for the Reduction of Carbonyl Compounds.

✍ Scribed by Harneet Kaur; Fabiano Kauer Zinn; Edwin D. Stevens; Steven P. Nolan

Publisher
John Wiley and Sons
Year
2004
Weight
144 KB
Volume
35
Category
Article
ISSN
0931-7597

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✍ Fan Jiang; David Bézier; Jean-Baptiste Sortais; Christophe Darcel 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 185 KB 👁 2 views

## Abstract Hydrosilylation with well defined piano‐stool iron(II) complexes bearing both N‐heterocyclic carbene and cyclopentadienyl ligands was accomplished with both aldehydes and ketones. Typically, the reduction of aldehydes exhibited good activities (full reduction at 30 °C in 3 h), whereas f