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N-Heterocyclic Carbene—Palladium Complexes as Efficient Catalysts for the Oxidative Carbonylation of Amines to Ureas.

✍ Scribed by Shuzhan Zheng; Xingao Peng; Jianming Liu; Wei Sun; Chungu Xia

Publisher
John Wiley and Sons
Year
2007
Weight
20 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract Hydrosilylation with well defined piano‐stool iron(II) complexes bearing both N‐heterocyclic carbene and cyclopentadienyl ligands was accomplished with both aldehydes and ketones. Typically, the reduction of aldehydes exhibited good activities (full reduction at 30 °C in 3 h), whereas f