N-Heterocyclic Carbene Piano-Stool Iron
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Fan Jiang; David Bézier; Jean-Baptiste Sortais; Christophe Darcel
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Article
📅
2011
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John Wiley and Sons
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English
⚖ 185 KB
👁 2 views
## Abstract Hydrosilylation with well defined piano‐stool iron(II) complexes bearing both N‐heterocyclic carbene and cyclopentadienyl ligands was accomplished with both aldehydes and ketones. Typically, the reduction of aldehydes exhibited good activities (full reduction at 30 °C in 3 h), whereas f