[N-(5-Chloro-2-oxidobenzylidene)-l-valinato-κ3O,N,O′]diphenyltin(IV)
✍ Scribed by Dong, Yan
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 402 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The Sn atom of the title compound, [Sn(C~6~H~5~)~2~(C~12~H~12~ClNO~3~)], is in a distorted SnNC~2~O~2~ trigonal–bipyramidal geometry and forms five- and six-membered chelate rings with the tridentate ligand. One phenyl group is disordered over two positions with occupancy factors 0.58 (3):0.42 (3).
📜 SIMILAR VOLUMES
(II)
The first homoleptic oxovanadium(IV)-histidine complex {systematic name: , adopts a distorted octahedral structure where one l-histidine ligand coordinates to the vanadium(IV) center in a tridentate fashion as a monoanion and the other in a bidentate fashion leaving a protonated imidazole group as
In the title complex, [Ni(C 14 H 11 N 3 OS)(C 5 H 5 N)], the Ni II atom is N,O,S-chelated by the deprotonated salicylaldimine-4phenylthiosemicarbazide dianion and is also coordinated by a pyridine molecule, the coordinating atoms giving rise to a square-planar geometry for the Ni atom. The asymmetri