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[N-Formyl-N′-(2-oxidobenzylidene)­hydrazine-κ3O,N,O′]diphenyl­tin(IV)

✍ Scribed by Shuja, Shaukat ;Ali, Saqib ;Meetsma, Auke ;Broker, Grant A. ;Tiekink, Edward R. T.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
251 KB
Volume
63
Category
Article
ISSN
1600-5368

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[N-(5-Chloro-2-oxidobenzylidene)-l-valin
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✍ Dong, Yan 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 402 KB

The Sn atom of the title compound, [Sn(C~6~H~5~)~2~(C~12~H~12~ClNO~3~)], is in a distorted SnNC~2~O~2~ trigonal–bipyramidal geometry and forms five- and six-membered chelate rings with the tridentate ligand. One phenyl group is disordered over two positions with occupancy factors 0.58 (3):0.42 (3).

Bis(2-fluorobenzyl)(N-salicylidenevalina
Bis(2-fluorobenzyl)(N-salicylidenevalinato-κ3N,O,O′)tin(IV)
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A sample of salicylidene-valine (1.0 mmol) and sodium methylate (1.0 mmol) was stirred in 20 ml dichloromethane at room temperature for 30 min. To this solution was added di(o-fluorobenzyl)tin dichloride (1.0 mmol). The mixture was stirred at 40°C under nitrogen for 18 h. Evaporation of the filtrate