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(l-Histidinato-κ3N,N,O)(l-histidine-κ2N,O)oxido­vanadium(IV) perchlorate monohydrate

✍ Scribed by Islam, Mohammad K. ;Tsuboya, Chieko ;Miyashita, Yoshitaro ;Okamoto, Ken-ichi ;Kanamori, Kan


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
142 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The first homoleptic oxovanadium(IV)-histidine complex {systematic name:

, adopts a distorted octahedral structure where one l-histidine ligand coordinates to the vanadium(IV) center in a tridentate fashion as a monoanion and the other in a bidentate fashion leaving a protonated imidazole group as a pendent group.

metal-organic papers m1054 Islam et al.


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