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Morphology and crystallographic properties of rubrene thin films grown on muscovite(0 0 1)

✍ Scribed by T. Djuric; A. Thierry; W. Grogger; Sh.M. Abd Al-Baqi; H. Sitter; R. Resel


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
494 KB
Volume
41
Category
Article
ISSN
1386-9477

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✦ Synopsis


Thin films of the organic semiconductor rubrene were deposited on muscovite (0 0 1) substrates by hot wall epitaxy. The morphology of rubrene thin films in combination with their crystallographic properties was characterized by transmission electron microscopy. The initial growth proceeds in a partially wetting regime where amorphous droplets are formed. Through diffusive interactions the droplets merge together in partially crystalline open networks. At a more advanced growth stage, spherulites are formed and a variety of crystalline morphologies appears. Platelet-and needle-like morphologies can be assigned to the orthorhombic phase of rubrene with the [3 0 1] and [11 0] zone axes, respectively.


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