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LIF detection of the CF3O radical and kinetics of its reactions with CH4 and C2H6

✍ Scribed by H. Saathoff; R. Zellner

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 469 KB
Volume: 206
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)85563-4

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✦ Synopsis

Fluorescence excitation and dispersed fluorescence spectra of the jz 'E-A 2A, transition of the trifluoromethoxy radical have been measured using laser excitation in the range 336-358 in. The spectra are dominated by the features of the CO stretching and the OCF deformation mode. The LIF technique has been used to study the kinetics of the reactions of CFsO (2 *E) radicals with CH, (5) and C,Hs (6). Rate coefficients of s= (2.2k0.2) X lo-i4 and h= (1.2t0.2) X 10-12cm3/s at 298 K have been determined

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