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Reactions of KrH+ and O2H+ with CH4, C2H4, C2H6 and NH3

โœ Scribed by R.D. Smith; J.H. Futrell

Publisher
Elsevier Science
Year
1976
Weight
425 KB
Volume
19
Category
Article
ISSN
0020-7381

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๐Ÿ“œ SIMILAR VOLUMES

Unimolecular reactions of the isolated i
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โœ Richard D. Bowen; Alex. W. Colburn; Peter J. Derrick ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 858 KB

The reactions of ten metastable immonium ions of general structure R'R2C=NH+C4H9 (R' = H, R2 = CH, , C2H, ; R' = R2 = CH,) are reported and discussed. Elimination of C4H, is usually the dominant fragmentation pathway. This process gives rise to a Gaussian metastable peak; it is interpreted in terms

Arrhenius parameters for the reactions C
Arrhenius parameters for the reactions CH3. + C4H10 โ†’ CH4 + C4H9. and C2H5. + C4H10 โ†’ C2H6 + C4H9.
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Study of n-butane pyrolysis at high temperature in a flow system allows measurement of the sum of the rate constants of the initiation reactions (2) and of the Arrhenius parameters of the reactions Established data for kl/k2 allow estimation of kl for 951'K and this, with recent thermochemical da