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Flow tube/LIF measurements of the rate constants for the reactions with NO of CF3O and CF3O2 radicals

✍ Scribed by C. Bourbon; M. Brioukov; B. Hanoune; J.P. Sawerysyn; P. Devolder

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 598 KB
Volume: 254
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(96)00277-1

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✦ Synopsis

The rate constants for the reactions CF302 + NO ~ CF30+NO 2 (1) and CF30+NO~ products (2) have been measured at room temperature using a fast flow reactor associated with a monitoring of CF30 radicals by laser induced fluorescence (LIF); for the measurement of k~, CF30 radicals are prepared by the discharge flow technique in the reactive system F/CF3H/OjNO; the average value is k t = (1.76 + 0.35)× 10-II cm 3 molecule-~ s-1. For reaction (2), CF30 radicals are prepared by another source: the thermolysis of the dimer CF3OOCF 3 and the derived rate constant is k 2 ~ (4.7 + 0.9)× 10 ~ cm 3 molecule-t s-~. Our results are in reasonable agreement with recent measurements using different techniques.

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