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Absolute rate constants for the reaction of CF3O2 and CF3O radicals with NO at 295 K

✍ Scribed by Jens Sehested; Ole John Nielsen

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 589 KB
Volume: 206
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)85567-8

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✦ Synopsis

Using a pulse radiolysis UV absorption technique and subsequent simulations of experimental NO1 and FNO absorption transients, rate constants for reaction between CF90 and CFsO2 radicals with NO were determined, CFp02+NO+CF,O+N02 (3 ), CF,OtNO~CF,OtFNO(5).k~wasderivedtobe(1.68~0.26)X10~~'cm3molecuIe~'s~L,andk~=(5.2f2.7)X1O~"cm3 molecule-' s-l. Results are discussed in the context of the atmospheric chemistry of halocarbons.

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