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Kinetics study of gas-phase reactions of erythro/threo-CF3CHFCHFC2F5 with OH radicals at 253–328 K

✍ Scribed by L. Chen; T. Uchimaru; S. Kutsuna; K. Tokuhashi; A. Sekiya

Book ID
108109076
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
226 KB
Volume
488
Category
Article
ISSN
0009-2614

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## Abstract Rate constants were determined for the reactions of OH radicals with halogenated cyclobutanes cyclo‐CF~2~CF~2~CHFCH~2~(__k__~1~), __trans__‐cyclo‐CF~2~CF~2~CHClCHF(__k__~2~), cyclo‐CF~2~CFClCH~2~CH~2~(__k__~3~), __trans__‐cyclo‐CF~2~CFClCHClCH~2~(__k__~4~), and __cis__‐cyclo‐CF~2~CF

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## Abstract The rate constants, __k__~1~, of the reaction of CF~3~OC(O)H with OH radicals were measured by using a Fourier transform infrared spectroscopic technique in an 11.5‐dm^3^ reaction chamber at 242–328 K. OH radicals were produced by UV photolysis of an O~3~–H~2~O–He mixture at an initial

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## Abstract Rate constants for the reactions of OH and NO~3~ radicals with CH~2~CHF (__k__~1~ and __k__~4~), CH~2~CF~2~ (__k__~2~ and __k__~5~), and CHFCF~2~ (__k__~3~ and __k__~6~) were determined by means of a relative rate method. The rate constants for OH radical reactions at 253–328 K were

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Erratum: “Rate constants for the gas-phase reaction of CF3CF2CF2CF2CF2CHF2 with OH radicals at 250–430 K”, Int J Chem Kinet 2004, 36, 26
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The value of k 1 in the paper should be (5.50 ± 0.79) × 10 -13 exp[-(1690 ± 60)/T ] cm 3 molecule -1 s -1 , and the tropospheric lifetime of CF 3 CF 2 CF 2 CF 2 CF 2 CHF 2 should be 33 years. The data in Table IV should be revised.