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Erratum: “Rate constants for the gas-phase reaction of CF3CF2CF2CF2CF2CHF2 with OH radicals at 250–430 K”, Int J Chem Kinet 2004, 36, 26

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
33 KB
Volume
42
Category
Article
ISSN
0538-8066

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✦ Synopsis

The value of k 1 in the paper should be (5.50 ± 0.79) × 10 -13 exp[-(1690 ± 60)/T ] cm 3 molecule -1 s -1 , and the tropospheric lifetime of CF 3 CF 2 CF 2 CF 2 CF 2 CHF 2 should be 33 years. The data in Table IV should be revised.

📜 SIMILAR VOLUMES

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reaction of CF3CF2CF2CF2CF2CHF2 with OH radicals at 250–430 K
✍ L. Chen; K. Tokuhashi; S. Kutsuna; A. Sekiya 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 128 KB 👁 1 views

## Abstract The rate constants __k__~1~ for the reaction of CF~3~CF~2~CF~2~CF~2~CF~2~CHF~2~ with OH radicals were determined by using both absolute and relative rate methods. The absolute rate constants were measured at 250–430 K using the flash photolysis–laser‐induced fluorescence (FP‐LIF) techni

Kinetics for the gas-phase reactions of
Kinetics for the gas-phase reactions of OH radicals with the hydrofluoroethers CH2FCF2OCHF2, CHF2CF2OCH2CF3, CF3CHFCF2OCH2CF3, and CF3CHFCF2OCH2CF2CHF2 at 268–308 K
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## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical

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The kinetics of the self-reactions of HO 2 , CF 3 CFHO 2 , and CF 3 O 2 radicals and the cross reactions of HO 2 with FO 2 , HO 2 with CF 3 CFHO 2 , and HO 2 with CF 3 O 2 radicals, were studied by pulse radiolysis combined with time resolved UV absorption spectroscopy at 295 K. The rate constants f

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## Abstract Rate constants for the gas‐phase reactions of CH~3~OCH~2~CF~3~ (__k__~1~), CH~3~OCH~3~ (__k__~2~), CH~3~OCH~2~CH~3~ (__k__~3~), and CH~3~CH~2~OCH~2~CH~3~ (__k__~4~) with NO~3~ radicals were determined by means of a relative rate method at 298 K. NO~3~ radicals were prepared by thermal d

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## Abstract Rate constants were determined for the reactions of OH radicals with halogenated cyclobutanes cyclo‐CF~2~CF~2~CHFCH~2~(__k__~1~), __trans__‐cyclo‐CF~2~CF~2~CHClCHF(__k__~2~), cyclo‐CF~2~CFClCH~2~CH~2~(__k__~3~), __trans__‐cyclo‐CF~2~CFClCHClCH~2~(__k__~4~), and __cis__‐cyclo‐CF~2~CF

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## Abstract Absolute rate coefficients for the gas‐phase reactions of CF~2~CFCl and (__E__/__Z__)‐CFClCFCl with O(^3^P) atoms have been measured at 298 K using a discharge flow tube coupled to a chemiluminescence detection system. The observed rate constant values are (4.5 ± 0.4) × 10^−13^ and (1