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Rate constants for the gas-phase reactions of cyclo-CXCXCF2CF2– (X=H, F) with OH radicals at a temperature range of 253–328K

✍ Scribed by Jia, Xiaoqing; Chen, Liang; Mizukado, Junji; Kutsuna, Shuzo; Tokuhashi, Kazuaki

Book ID
122684183
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
582 KB
Volume
572
Category
Article
ISSN
0009-2614

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📜 SIMILAR VOLUMES

Kinetics of the gas-phase reactions of c
Kinetics of the gas-phase reactions of cyclo-CF2CFXCHXCHX – (X = H, F, Cl) with OH radicals at 253–328 K
✍ L. Chen; T. Uchimaru; J. Mizukado; S. Kutsuna; K. Tokuhashi; A. Sekiya 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 299 KB 👁 2 views

## Abstract Rate constants were determined for the reactions of OH radicals with halogenated cyclobutanes cyclo‐CF~2~CF~2~CHFCH~2~(__k__~1~), __trans__‐cyclo‐CF~2~CF~2~CHClCHF(__k__~2~), cyclo‐CF~2~CFClCH~2~CH~2~(__k__~3~), __trans__‐cyclo‐CF~2~CFClCHClCH~2~(__k__~4~), and __cis__‐cyclo‐CF~2~CF

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reaction of CF3CF2CF2CF2CF2CHF2 with OH radicals at 250–430 K
✍ L. Chen; K. Tokuhashi; S. Kutsuna; A. Sekiya 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 128 KB 👁 1 views

## Abstract The rate constants __k__~1~ for the reaction of CF~3~CF~2~CF~2~CF~2~CF~2~CHF~2~ with OH radicals were determined by using both absolute and relative rate methods. The absolute rate constants were measured at 250–430 K using the flash photolysis–laser‐induced fluorescence (FP‐LIF) techni

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reactions of OH radicals with CH3CHF2 and CHC12CF3 over the temperature range 295–388 K
✍ Ole J. Nielsen 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 392 KB

Rate constants for the reactions of OH radicals with CH,CHF, and CHCI,CF, have been determined over the temperature range 295-388 K and a total pressure of 1 atm. The OH rate data were obtained using the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy.

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reaction of OH radicals with a series of ketones at 299 ± 2 K
✍ Roger Atkinson; Sara M. Aschmann; William P. L. Carter; James N. Pitts Jr. 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 475 KB 👁 1 views

## Abstract Relative rate constants for the reaction of OH radicals with a series of ketones have been determined at 299 ± 2 K, using methyl nitrite photolysis in air as a source of hydroxyl radicals. Using a rate constant for the reaction of OH radicals with cyclohexane of 7.57 × 10^−12^ cm^3^ mol

Erratum: “Rate constants for the gas-pha
Erratum: “Rate constants for the gas-phase reaction of CF3CF2CF2CF2CF2CHF2 with OH radicals at 250–430 K”, Int J Chem Kinet 2004, 36, 26
📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 33 KB 👁 1 views

The value of k 1 in the paper should be (5.50 ± 0.79) × 10 -13 exp[-(1690 ± 60)/T ] cm 3 molecule -1 s -1 , and the tropospheric lifetime of CF 3 CF 2 CF 2 CF 2 CF 2 CHF 2 should be 33 years. The data in Table IV should be revised.