## Abstract Azulene, which is isomeric with naphthalene, was studied to determine whether it behaves like a polycyclic aromatic hydrocarbon or an alkene in its gas‐phase reactions with OH and NO~3~ radicals and O~3~. Using relative rate methods, rate constants for the reactions of azulene with OH a
Kinetics of the gas-phase reactions of alkylnaphthalenes with O3, N2O5 and OH radicals at 298 ± 2 K
✍ Scribed by Roger Atkinson; Sara M Aschmann
- Book ID
- 113123161
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 463 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0004-6981
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📜 SIMILAR VOLUMES
Rate constants for the reactions of 0 3 and OH radicals with furan and thiophene have been determined at 298 f 2 K. The rate constants obtained for the 0 3 reactions were (2.42 f 0.28) X 1O-lS cm3/molec.s for furan and <6 X cm3/molec-s for thiophene. The rate constants for the OH radical reactions,
The rate constants for the reactions OH(X 'II, kl k2 u=O) + NH3 --t HzO+ NH? and OII(X '11, u=O) + O3 -HO, + O2 were measured at 296K by the flash photolysis resonance fluorescence technique. The values of the rate constants thus obtained are kl = (4.1 +-0.6) X lo-l4 nndkz = (6.5 t 1.0) X lo-l4 in u
Rate constants for the gas-phase reactions of the biogenically emitted monoterpene p-phellandrene with OH and NO3 radicals and O3 have been measured at 297 f 2 K and atmospheric pressure of air using relative rate methods. The rate constants obtained were (in cm3 molecule-' s-' units): for reaction
Plash photolysis kinetic absorption spectroscopy was used to investigate the gas phase reaction between hydroperoxy (HO,) and methylperoxy (CH302) radicals at 298 K. Due to the large difference between the self-reactivities of the two radicals, firstor second-order kinetic conditions could not be ma
The kinetics of the gas-phase reactions of the OH radical with (C,H,O),PO and (CH30)2P(S)C1 and of the reactions of NO, radicals and O3 with (CH,O),P(S)Cl have been studied at room temperature. Using a relative rate technique, the rate constants determined for the reactions of the OH radical with (C