✦ LIBER ✦

Kinetics of the reaction of O(3P) with CF3NO

✍ Scribed by R. P. Thorn; J. M. Nicovich; J. M. Cronkhite; S. Wang; P. H. Wine

Publisher: John Wiley and Sons
Year: 1995
Tongue: English
Weight: 580 KB
Volume: 27
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550270408

No coin nor oath required. For personal study only.

✦ Synopsis

A laser flash photolysis-resonance fluorescence technique has been employed to study the kinetics of the reaction of O(3P) with CF3NO (kz) as a function of temperature. Our results are described by the Arrhenius expression k z ( T ) = (4.54 ? 0.70) X 10-12exp[(-560 i 46)/T] cm3molecule-'s-' (243 K 5 T 5 424 K); errors are 2 ~7 and represent precision only. The O(3P) + CF3NO reaction is sufficiently rapid that CF3NO cannot be employed as a selective quencher for Oz(a'A,) in laboratory systems where O(3P) and Oz(a'A,) coexist, and where O(3P) kinetics are being investigated.

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