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Kinetic study of the reaction CF3O+O3→CF3O2+O2

✍ Scribed by Timothy J. Wallington; Michael D. Hurley; William F. Schneider

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
629 KB
Volume
213
Category
Article
ISSN
0009-2614

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✦ Synopsis

A relative rate approach has , been used to measure the reactivity of CF,O radicals towards ozone. Using k(CFaO+NOa)=2,7x IO-" cm' molecule-' s-' as the referencereactioqanupperlimit ofk(CF,O+Os) 63~ 10-'4cmSmolecule-' was determined at 295 K and 700 Torr of O2 diluent. The implications for the atmospheric chemistry of HFCs are discussed.

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