✦ LIBER ✦

Kinetics of the reaction of CF3O2 with NO

✍ Scribed by I.C. Plumb; K.R. Ryan

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 201 KB
Volume: 92
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)80267-4

No coin nor oath required. For personal study only.

✦ Synopsis

The rare cocificwn ior the rcact~on oiCF,02 with NO has been mcasurcd at 295 R m hcbum usins 3 ilow tube nmplcd by 2 rnxs spcctromurcr The KIIUC obrlmed ior this raw coeiircicnt was (17 8 f 3 6) x IO-'* crK3 s-t and iound to bc indcpcndcnr of [Hc] over the range (6 3-16 8) x lOI cmm3. Tbls value is 3pproulmxcly 3 ixtur of 2 higher than carher measurcmcnts of the rate cociiictcnts ior CH,O, and C2HS02 with NO and mdic;ltes that further measurements arc rcquued for this lmportzmt cbss of rzxtions 1. hroduction lntercs.1 UI the gas-phase rcnctions of pero.u> radicals

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