## Abstract A direct kinetics study of the temperature dependence of the CH~2~O branching channel for the CH~3~O~2~ + HO~2~ reaction has been performed using the turbulent flow technique with highβpressure chemical ionization mass spectrometry for the detection of reactants and products. The temper
Kinetics of the CH 3 O 2 + NO Reaction: Temperature Dependence of the Overall Rate Constant and an Improved Upper Limit for the CH 3 ONO 2 Branching Channel
β Scribed by Scholtens, Kurtis W.; Messer, Benjamin M.; Cappa, Christopher D.; Elrod, Matthew J.
- Book ID
- 126773525
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 95 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The CHsOs radical was generated by pulsed laser photolysis and was detected directly by photoionization mass spectrometry. The radical was photoionized by the Ar resonance lines ( 11.62 and 11.83 eV) and detected as the parent ion, CHsO: . Reactions of CH302 and CDs02 with NO were studied by time-re
Flash photolysis kinetic absorption spectroscopy was used to investigate the gas phase disproportionation reaction of CH302 radicals over the temperature range 228-380 K at pressures between 50 and 400 Torr of nitrogen diluent. The measured secondorder rate constants, defined by the expression -d[ C
The reaction of NO with the peroxy radical CFC12CH202, and with CH3CFClO2 was investigated at 8-20 torr and 263-321 K by UV flash photolysis of CFCI2CH3/O2/NO gas mixtures The kinetics were determined from observations of the growth rate of the CFC12CH20 radical and the decay rate of NO by time-reso