Kinetics of the C 2 H 5 O 2 + NO x Reactions: Temperature Dependence of the Overall Rate Constant and the C 2 H 5 ONO 2 Branching Channel of C 2 H 5 O 2 + NO
β Scribed by Ranschaert, Dana L.; Schneider, Nicholas J.; Elrod, Matthew J.
- Book ID
- 127204224
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 104 KB
- Volume
- 104
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
The rate coefficients for the gas-phase reactions of C,H,O;, and n-C3H,0, radicals with NO have been measured over the temperature range of (201 -403) K using chemical ionization mass spectrometric detection of the peroxy radical. The alkyl peroxy radicals were generated by reacting alkyl radicals w
The overall rate constant for the reaction between ethylperoxy radicals and nitric oxide has been directly measured by flash photolysis and kinetic spectroscopy. At room temperature the rate constant k 7 = (1.6\* 0.1) X 10' litremole-' F' has been assigned to the reaction C2H502 + NO + CzHsO + NO\*\