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Comment on “Rate Constants for CH 3 + O 2 → CH 3 O + O at High Temperature and Evidence for H 2 CO + O 2 → HCO + HO 2 ” and “Rate Coefficient Measurements of the Reaction CH 3 + O 2 = CH 3 O + O”

✍ Scribed by Eiteneer, Boris; Frenklach, Michael


Book ID
126172324
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
23 KB
Volume
104
Category
Article
ISSN
1089-5639

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The decomposition of dimethyl peroxide (DMP) was studied in the presence and absence of added NO, to determine rate constants k l and k z in the temperature range of 391-432OK: The results reconcile the studies by Takezaki and Takeuchi, Hanst and Calvert, and Batt and McCulloch, giving log kl(sec-1