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Kinetics and mechanism of a fast leuco-Methylene Blue oxidation by copper(ii)–halide species in acidic aqueous media

✍ Scribed by Impert, Olga; Katafias, Anna; Kita, Przemysław; Mills, Andrew; Pietkiewicz-Graczyk, Aleksandra; Wrzeszcz, Grzegorz


Book ID
118218138
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
155 KB
Volume
3
Category
Article
ISSN
1477-9226

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Mechanism of oxidation of iron(II) chela
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Oxidation of the Fe n chelates [FeL l (L = phen or bipy) by Cr w and Mn TM in H2SO 4 medium was found to proceed through the formation of a bimetallic insertion complex which decomposes in the slow step, followed by electron transfer from [FeLl to the oxidant. The reactions are catalysed by both ani