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Kinetics and mechanism of the oxidation of uranium(IV) by hypochlorous acid in aqueous acidic perchlorate media

✍ Scribed by Silverman, Robert A.; Gordon, Gilbert.


Book ID
127125717
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
699 KB
Volume
15
Category
Article
ISSN
0020-1669

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Kinetics and mechanism of the cerium (IV
✍ Samir B. Hanna; Jeff Taylor Fenton πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 English βš– 673 KB

## Abstract The Ce(IV) oxidation of the five‐, six‐, and seven‐membered ring α‐hydroxycycloalkanecarboxylic (C5, C6, and C7) acids to the corresponding cyclic ketones has been studied in acidic perchlorate media. The data may be interpreted in terms of a mechanism which involves fast preequilibrium