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Kinetics and mechanism of oxidation of some nickel(II)–imine–oxime complexes by peroxodisulfate in aqueous acidic solutions

✍ Scribed by Farah, Shereen F. A.; Sulfab, Yousif; Adnan, Rohana

Book ID
121550051
Publisher
Springer
Year
2014
Tongue
English
Weight
344 KB
Volume
39
Category
Article
ISSN
0340-4285

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The kinetics of the oxidation of formate, oxalate, and malonate by [Ni III (L 1 )] 2ϩ (where HL 1 ϭ 15-amino-3-methyl-4,7,10,13-tetraazapentadec-3-en-2-one oxime) were carried out over the regions pH 3.0 -5. 75, 2.80 -5.50, and 2.50 -7.58, respectively, at constant ionic strength and temperature 40Њ