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Kinetics of electron transfer between nickel (IV) oxime-imine complexes and sulphur(IV) in aqueous media

✍ Scribed by Santanu Bhattacharya; Mahammad Ali; Pradyot Banerjee


Book ID
112934900
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1994
Tongue
English
Weight
29 KB
Volume
106
Category
Article
ISSN
0253-4134

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Studies in nickel(IV) chemistry. Electro
✍ R. Sahu; G. Neogi; S. Acharya; R. K. Panda πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 English βš– 534 KB

The kinetics of electron transfer from hexacyanoferrate(I1) to tris(dimethylg1yoximato)nickelate(IV), Ni(dmg)g-, to produce Fe(CN)t-and Ni(dmgH)2, follows a pseudo-first-order disappearance in the Ni(1V). The pseudo-first-order rate constants hob8 are linearly dependent on [Fe(CN);-]o in a fiftyfold